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Preheat oven: Set your oven to 400°F (200°C).
Prepare cabbage: Cut cabbage into 6-8 wedges, leaving the core intact.
Make marinade: Combine olive oil, balsamic vinegar, garlic, salt, pepper, smoked paprika, thyme, and oregano in a bowl.
Marinate cabbage: Toss cabbage wedges in the marinade to coat evenly.
Bake: Place cabbage wedges on a baking sheet. Cover with foil and bake for 20 minutes. Remove foil and bake for an additional 20-25 minutes, or until tender and crispy.
Serve: Sprinkle with Parmesan cheese (optional) and enjoy!
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